The Structure of [η<sub>3</sub>-C<sub>3</sub>H<sub>5</sub>PdP(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>]<sub>2</sub> - Concepedia

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The Structure of [η<sub>3</sub>-C<sub>3</sub>H<sub>5</sub>PdP(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>]<sub>2</sub>

DOI Full Paper Access

25

Citations

0

References

1980

Year

P.W. Jolly, Carl Krüger, K. P. Schick, GUENTHER WILKE

Zeitschrift für Naturforschung B

Pd-pd BondMathematical ChemistryOrganometallic CatalysisMain Group ChemistryChemistryη 3Title CompoundDerivative (Chemistry)

Abstract

The 1:1 adduct formed by triphenylphosphine with bis(η 3 -allyl)palladium disproportionates at 0 °C in toluene to give the title compound. A crystal structure determination confirms the presence of a Pd-Pd bond and bridging η 3 -allyl groups