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SPECIFIC HEATS OF MANGANESE AND BISMUTH AT LIQUID HYDROGEN TEMPERATURES
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1949
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EngineeringExperimental ThermodynamicsChemistryThermal ConductivityElectronic Specific HeatThermal AnalysisThermophysicsThermodynamicsThermal ConductionMaterials ScienceSpecific HeatsPhysicsPhysical ChemistryHydrogenHeat TransferSimple Cubic LatticeHydrogen TransitionNatural SciencesApplied PhysicsCondensed Matter PhysicsThermal EngineeringThermophysical PropertyThermal Property
New measurements of the specific heats of manganese and bismuth in the temperature range 14° to 22° K. are reported. The specific heats of these metals are compared with theory. In both cases the approximate theoretical formula[Formula: see text]where C D (x) is the Debye function, is accurately obeyed over the limited temperature region concerned. However, comparison with measurements at other temperatures shows that this may lead to erroneous conclusions. For manganese a precise conclusion is not possible, and it is estimated that the electronic specific heat coefficient A lies between 0.0035 and 0.0040, while θ varies with temperature from 365 to 390 degrees. For bismuth it is concluded that the electronic specific heat is negligible. This permits an accurate determination of θ, and it is found that the variation of θ with temperature is remarkably similar to that predicted by Blackman for a simple cubic lattice.