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β‘ ‘-(BEDT-TTF)<sub>4</sub>[(H<sub>3</sub>O)Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]CH<sub>2</sub>Cl<sub>2</sub>:  Effect of Included Solvent on the Structure and Properties of a Conducting Molecular Charge-Transfer Salt

DOI

45

Citations

10

References

2001

Year

Samina Rashid, Scott S. Turner, D. Le Pévelen, Peter Day, Mark E. Light, Michael B. Hursthouse, Steven Firth, Robin J. H. Clark
Inorganic Chemistry

Abstract

The new charge-transfer salt β‘ ‘-(BEDT-TTF)4[(H3O)Cr(C2O4)3]S, where BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene and S = CH2Cl2, has a broad metal−insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate series, notably the superconducting materials with S = PhCN and the salt with S = C5H5N, which has a sharp metal−insulator transition.

References

YearCitations

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