ACS Applied Materials & Interfaces · 2012 · 117 citations · 36 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials ChemistryNanomaterialsNanotechnologyCatalytic MaterialsMetal Oxide NanomaterialsNanocatalysisNanomaterials SynthesisPhotocatalysisPhotochemistryMetal Oxide NanocatalystsMicrospheresNanostructured PhotocatalystsPhotocatalytic DegradationPhotocatalytic MaterialsPhotocatalytic NanomaterialsSolvothermal SynthesisSurface Area
Anatase type nitrogen-fluorine (N-F) codoped TiO(2) nanobelts were prepared by a solvothermal method in which amorphous titania microspheres were used as the precursors. The as-prepared TiO(2) nanobelts are composed of thin narrow nanobelts and it is noted that there are large amount of wormhole-like mesopores on these narrow nanobelts. Photocatalytic activity of the N-F codoped TiO(2) nanobelts was measured by the reaction of photocatalytic degradation of methyl orange. Results indicate that the photocatalytic activity of the N-F codoped TiO(2) nanobelts is higher than that of P25, which is mainly ascribed to wormhole-like mesopores like prison, larger surface area, and enhanced absorption of light due to N-F codoping. Interestingly, it is also found that the photocatalytic activity can be further enhanced when tested in a new testing method because more photons can be captured by the nanobelts to stimulate the formation of the hole-electron pair.
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Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides
Ryoji Asahi, Takeshi Morikawa, Takeshi Ohwaki et al. · Science · 2001 · 12.2K citations
Vaidyanathan Subramanian, Eduardo E. Wolf, Prashant V. Kamat · Journal of the American Chemical Society · 2004 · 2K citations · Full text