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Expedient conversion of d-glucose into 1,5-anhydro-d-fructose and into single stereogenic-center dihydropyranones, suitable six-carbon scaffolds for concise syntheses of the soft-coral constituents (−)-bissetone and (−)-palythazine

BiosynthesisEngineeringEnantioselective SynthesisBiochemistryNatural SciencesDiversity-oriented SynthesisOrganic ChemistrySingle Stereogenic-center DihydropyranonesSoft-coral ConstituentsStereoselective SynthesisChemistryNatural Product SynthesisSynthetic ChemistrySuitable Six-carbon Scaffolds