Optical Surface Phonons in Zinc Oxide Detected by Slow-Electron Spectroscopy

Abstract

Scattering of electrons from surfaces of ZnO single crystals has been studied in ultrahigh vacuum with a high-resolution electron-impact spectrometer ($\ensuremath{\Delta}E<20$ meV, impact energy ${E}_{0}=1\ensuremath{-}100$ eV). The energy-loss spectrum in specular reflection shows a series of equally spaced loss peaks. The characteristic loss energies [68.8 meV for the ($1\overline{1}00$) surface and 67.3 meV for the (0001) and the ($000\overline{1}$) surfaces] agree with the energies of optical surface phonons determined by the condition $\mathrm{Re}{\ensuremath{\epsilon}}_{n}(\ensuremath{\omega})=\ensuremath{-}1$.