Publication | Closed Access
Weak complexes of sulphur and selenium. Part II. Complex species of SO2, SOCl2, and SO2Cl2 with the thiocyanate ligand
13
Citations
0
References
1973
Year
Complex SpeciesInorganic ChemistryChemical EngineeringWeak ComplexesEngineeringBiochemistryScn– LigandNatural SciencesCoordination ComplexCharge-transfer TypeMolecular ComplexChemistrySupramolecular ChemistryInorganic SynthesisPart IiInorganic Compound
The formation of 1 : 1 complex species between SO2, SOCl2, and SO2Cl2 with the SCN– ligand is reported in dilute solutions. Their thermodynamic constants point to a weak association of a charge-transfer type. The nature of the complex species is discussed in relation to polarisability and basicity of the SCN– ligand.