Concepedia

Thermoinitiated Cationic Polymerization of Styrene with a Pyridinium Salt

Hitomi Uno, Toshikazu Takata, Takeshi Endo

Chemistry Letters · 1988 · 25 citations · 9 references

DOI

Concepts

Abstract

Abstract N-Benzyl-p-cyanopyridinium hexafluoroantimonate behaved as a thermally latent catalyst to initiate the cationic polymerization of styrene at 120 °C leading to polystyrene possessing a bimodal molecular weight distribution.

References

9

Photoinitiated cationic polymerization with triarylsulfonium salts

James V. Crivello, J. H. W. Lam · Journal of Polymer Science Polymer Chemistry Edition · 1979 · 298 citations

, , +14

Thermoinitiated cationic polymerization of epoxy resins by sulfonium salts

Kazuhiko Morio, Hisashi Murase, Hiroshi Tsuchiya et al. · Journal of Applied Polymer Science · 1986 · 89 citations

, , +10

Photoinitiated cationic polymerization by dialkylphenacylsulfonium salts

James V. Crivello, J. H. W. Lam · Journal of Polymer Science Polymer Chemistry Edition · 1979 · 83 citations

, , +8

Thermoinitiated cationic polymerization of bicyclo ortho ester by benzylsulfonium salts

Takeshi Endo, Hitomi Uno · Journal of Polymer Science Polymer Letters Edition · 1985 · 76 citations

, , +14

Cationic polymerization of styrene by acetyl perchlorate: Molecular weight distribution of polystyrene and nature of the propagating species

Toshinobu Higashimura, Osamu Kishiro · Journal of Polymer Science Polymer Chemistry Edition · 1974 · 60 citations

, , +17