Concepedia

Regiodivergent Metal-Catalyzed Rearrangement of 3-Iminocyclopropenes into N-Fused Heterocycles

Stepan Chuprakov, Vladimir Gevorgyan

Organic Letters · 2007 · 206 citations · 30 references

DOI

Concepts

Abstract

A highly efficient regiodivergent method for the synthesis of N-fused heterocycles via transition-metal-catalyzed rearrangement of 3-iminocyclopropenes has been developed.

References

30

Rh‐Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles

Stepan Chuprakov, Frank W. Hwang, Vladimir Gevorgyan · Angewandte Chemie International Edition · 2007 · 343 citations

, , +14

Catalytic Enantioselective Hydroboration of Cyclopropenes

Marina Rubina, Michael Rubin, Vladimir Gevorgyan · Journal of the American Chemical Society · 2003 · 306 citations

, , +12

Strain Energy of Small Ring Hydrocarbons. Influence of C−H Bond Dissociation Energies

Robert D. Bach, Olga Dmitrenko · Journal of the American Chemical Society · 2004 · 293 citations

, , +11

Gold-Catalyzed 1,2-Migration of Silicon, Tin, and Germanium en Route to C-2 Substituted Fused Pyrrole-Containing Heterocycles

Vladimir Gevorgyan · Journal of the American Chemical Society · 2006 · 285 citations · Full text

, , +16

Potent Inhibitors of Secretory Phospholipase A2:  Synthesis and Inhibitory Activities of Indolizine and Indene Derivatives

Sanji Hagishita, Masaaki Yamada, Kazuhiro Shirahase et al. · Journal of Medicinal Chemistry · 1996 · 224 citations · Full text

, , +13