The symmetric broadening of the water relaxation peak in polymer–water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers

Abstract

The dielectric relaxation of water molecules in polymer–water mixtures is discussed. The memory function approach and scaling relationships are used as a basis for the model of symmetric dielectric spectrum broadening. The correspondence between the relaxation time, the geometrical properties, the self-diffusion coefficient, and the Cole–Cole exponent is established. The relationship between the hydrophilic and hydrophobic properties of the polymers and the dielectric relaxation parameters is discussed.