Photoresponsive rolling and bending of thin crystals of chiral diarylethenes

Kingo Uchida, S. Sukata, Yuji Matsuzawa, Masako Akazawa, Jaap J. D. de Jong, Nathalie Katsonis, Yuko Kojima, Shinichiro Nakamura, Jetsuda Areephong, Auke Meetsma,

Chemical Communications · 2007 · 147 citations · 13 references

DOIFull text

Open access

Concepts

Abstract

Dithienylhexafluorocyclopentene with (R)- or (S)-N-phenylethylamide substituents formed rod-like and 0.2-1.0 microm-thick platelike crystals by sublimation; upon UV irradiation, the crystals bent concavely to the incident light and finally rolled crystals were obtained; the bent crystals were reconverted to flat crystals by visible light irradiation.

References

13