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Accurate amplitudes for electron-impact ionization
113
Citations
19
References
2001
Year
Flux-extrapolation MethodEngineeringRearrangement FormalismPhysicsFlux ExtrapolationNatural SciencesElectron SpectroscopyAccurate AmplitudesApplied PhysicsAtomic PhysicsPhysical ChemistryElectron DiffractionComputational ChemistryQuantum ChemistryIon EmissionMolecular Fragmentation
We show that the ``two-potential'' formalism of conventional distorted-wave rearrangement theory, which is formally valid only for short-range interactions, can be used to evaluate amplitudes for the ionization of atomic hydrogen by electron impact. The triply differential cross sections calculated using this method validate earlier results obtained by extrapolating the quantum mechanical flux. Although it uses the same time-independent wave functions, this method offers significant advantages over flux extrapolation. It is more accurate, can be applied in practical calculations over a broader range of collision energies, and unlike the flux-extrapolation method, can be applied for arbitrary values of energy sharing between the ejected electrons. Since this rearrangement formalism provides the complete scattering amplitude for ionization, it can be used to calculate any differential cross section.
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