Organometallics · 2010 · 14 citations · 45 references
Natural SciencesChemistryMedicinal ChemistryInorganic ChemistryOrganic ChemistryOrganometallic ChemistryChemical BondingCoordination ChemistryLanthanide ChemistryMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesC-h Bond ActivationLanthanide ChelationLanthanide ComplexesLanthanide Coordination ChemistryLanthanide Organometallic ChemistryLigand Effects On ReactivityQuinoline ChemistryQuinoline Synthesis
Reaction of Ln[N(TMS) 2 ] 3 with a stoichiometric amount of HL (HL = 3,5-Bu t 2 -2-(OH)-C 6 H 2 CH═N-8-C 9 H 6 N) at 40 °C resulted in the new complexes L′Ln(THF)·THF (Ln = Y(1), Yb(2); L′ = [3,5-Bu t 2 -2-(O)-C 6 H 2 CH═N-8- C 9 H 6 N 3,5-Bu t 2 -2-(O)-C 6 H 2 CH-(N)-8-C 9 H 6 N] 3− ) via metalation of a ligand quinoline ring in L 2 LnN(TMS) 2 formed in situ, followed by the attack of the newly formed aryl species at the imine group of the second ligand.
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Efficient Activation of Aromatic C-H Bonds for Addition to C-C Multiple Bonds
Chengguo Jia, Dongguo Piao, Juzo Oyamada et al. · Science · 2000 · 819 citations
Mark E. Thompson, Steven M. Baxter, A. Ray Bulls et al. · Journal of the American Chemical Society · 1987 · 800 citations