Prediction of specific heat of organic liquids

Abstract

Abstract A theoretical equation is presented for predicting the specific heat at constant volume and constant pressure of organic liquids as a function of temperature from data on the velocity of sound, infrared and Raman spectra. By use of this equation, the average deviation of the calculated from the experimental values of specific heat for 100 organic liquids at 68°F. is ±1.5%. An alternate correlation for hydrocarbon liquids based on a modified statement of the theory of corresponding states is also presented. Based on it, the average deviation of the calculated from the experimental values for 100 points representing the entire temperature range is ±0.9%.