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Unsaturated Tin Compounds: Generation and Reactivity of Me<sub>2</sub>Sn = C(SiMe<sub>3</sub>)<sub>2</sub> and Me<sub>2</sub>Sn = N(Si<i>t</i>Bu<sub>2</sub>Me)
44
Citations
4
References
1991
Year
Materials ScienceInorganic ChemistryEngineeringStannaethene 1HeterocyclicSolid-state ChemistryTin CompoundsOrganic ChemistryStannanimine 2Salt EliminationChemistryHeterocycle ChemistryNatural Product SynthesisInorganic MaterialSynthetic ChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
Stannaethene 1, which is hardly stabilized electronically, was obtained by salt elimination and its existence was shown by trapping reactions with 2,3-dimethylbutadiene and azido(di-tert-butyl) methylsilane. Stannanimine 2, formed from the azidosilane, can be “stored” as the cycloadduct 3.
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