Concepedia

Unsaturated Tin Compounds: Generation and Reactivity of Me<sub>2</sub>Sn = C(SiMe<sub>3</sub>)<sub>2</sub> and Me<sub>2</sub>Sn = N(Si<i>t</i>Bu<sub>2</sub>Me)

Nils Wibeŕg, Sham‐Kumar Vasisht

Angewandte Chemie International Edition in English · 1991 · 44 citations · 4 references

DOI

Concepts

Abstract

Stannaethene 1, which is hardly stabilized electronically, was obtained by salt elimination and its existence was shown by trapping reactions with 2,3-dimethylbutadiene and azido(di-tert-butyl) methylsilane. Stannanimine 2, formed from the azidosilane, can be “stored” as the cycloadduct 3.

References

4

Stable germa- and stannaethenes

A. Berndt, Hans‐Jürgen Meyer, Gerhard Baum et al. · Pure and Applied Chemistry · 1987 · 65 citations · Full text

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Unsaturated silicon compounds. 15. Compounds of silicon 67. Structure of the stable silaethene Me2Si:C(SiMe3)(SiMe(tert-Bu2)

Nils Wibeŕg, Gerhard Wagner, J. Riede et al. · Organometallics · 1987 · 52 citations

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1,1,3,3-tetramethyl-2,2,4,4-tetrakis(trimethylsilyl)-1,3- disilacyclobutane and its 1,3-digerma and 1,3-distanna analogs: Unexpected products from the reaction of bis(trimethylsilyl)bromomethyllithium with dimethyldihalo derivatives of silicon, germanium and tin

Dietmar Seyferth, J. L. Lefferts · Journal of Organometallic Chemistry · 1976 · 40 citations

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Strukturchemie ungesättigter Siliciumverbindungen: Kristall- und Molekülstrukturen des stabilen Silanimins ′Bu<sub>2</sub>Si=N—Si′Bu<sub>3</sub> und von Silanimin-Donoraddukten (Donor = Tetrahydrofuran, Benzophenon) / Structural Chemistry of Unsaturated Silicon Compounds: Crystal and Molecular Structures of the Stable Silaneimine ′Bu<sub>2</sub>Si=N—Si′Bu<sub>3</sub> and of Silaneimine Donor Adducts (Donor = Tetrahydrofuran, Benzophenone)

Gabriele Reber, Jürgen Riede, Nils Wibeŕg et al. · Zeitschrift für Naturforschung B · 1989 · 30 citations · Full text

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