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Rhodium–platinum cluster compounds. Relationships with olefin–platinum complexes and X-ray crystal structures of [PtRh<sub>4</sub>(µ-CO)<sub>4</sub>(η-C<sub>5</sub>Me<sub>5</sub>)<sub>4</sub>] and [PtRh<sub>2</sub>(µ-H)(µ-CO)<sub>2</sub>(CO)(PPh<sub>3</sub>)(η-C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>][BF<sub>4</sub>]
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1981
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Materials ScienceInorganic ChemistryChemical EngineeringCluster ScienceEngineeringCoordination ComplexDirhodium–platinum SpeciesRhodium–platinum Cluster CompoundsCluster ChemistryNovel Dynamic BehaviourMain Group ChemistryMolecular ComplexChemistryX-ray Crystal StructuresCrystallographyInorganic SynthesisX Ray DiffractionOlefin–platinum Complexes
The cluster compounds [PtRh4(µ-CO)4(η-C5Me5)4] and [PtRh2(µ-H)(µ-CO)2(CO)(PPh3)(η-C5Me5)2][BF4] have been prepared and their structures established by X ray diffraction; the dirhodium–platinum species undergoes novel dynamic behaviour in solution, revealed by n.m.r. studies, as do other salts of this type.