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Synthesis of 2S,5S-and 2R,5S-5-hydroxypipecolic acid via amide-methylenation of S-5-hydroxy-2-piperidone with dimethyltitanocene.

Natural Product SynthesisBioorganic ChemistryNatural SciencesOrganic ChemistryStereoselective SynthesisChemistryPharmacologySynthetic ChemistryEnantioselective Synthesis2S,5s-and 2R,5s-5-hydroxypipecolic Acid