Concepedia

Toward Dendrimers with Cylindrical Shape in Solution

Birol Karakaya, Wilhelm Claussen, K. Gessler, Wolfram Saenger, A. Dieter Schlüter

Journal of the American Chemical Society · 1997 · 201 citations · 11 references

DOI

Concepts

Abstract

Three approaches for the synthesis of dendrimers with poly( p -phenylene)-PPP derived cores are described. The respective limitations of these approaches are assessed in view of the goal of this research: to make available structurally perfect, high molecular weight polymers with a dense sequence of sterically demanding dendrons.

References

11

Starburst Dendrimers: Molecular‐Level Control of Size, Shape, Surface Chemistry, Topology, and Flexibility from Atoms to Macroscopic Matter

Donald A. Tomalia, Adel M. Naylor, William A. Goddard · Angewandte Chemie International Edition in English · 1990 · 3.2K citations

, , +12

Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules

Craig J. Hawker, Jean M. J. Fréchet · Journal of the American Chemical Society · 1990 · 2.4K citations

, , +15

Synthetic methods and reactions. 62. Transformations with chlorotrimethylsilane/sodium iodide, a convenient in situ iodotrimethylsilane reagent

George A. Olah, Subhash C. Narang, B. G. B. GUPTA et al. · The Journal of Organic Chemistry · 1979 · 462 citations

, , +4

Dendrimers: From Generations and Functional Groups to Functions

Jörg Issberner, Rolf Moors, Fritz Vögtle · Angewandte Chemie International Edition in English · 1995 · 292 citations

, , +7

Soluble poly(para-phenylene)s. 2. Improved synthesis of poly(para-2,5-di-n-hexylphenylene) via Pd-catalysed coupling of 4-bromo-2,5-di-n-hexylbenzeneboronic acid

Matthias Rehahn, A. Dieter Schlüter, Gerhard Wegner et al. · Polymer · 1989 · 275 citations

, , +7