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Palladium-catalysed asymmetric hydroalkenylation of norbornene
42
Citations
11
References
1994
Year
Asymmetric CatalysisChemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisEthenyl Triflate 5Organic ChemistryCatalysisChemistryCatalytic Asymmetric HydroalkenylationChiral CatalystEnantioselective SynthesisCatalytic SynthesisPalladium-catalysed Asymmetric Hydroalkenylation
Catalytic asymmetric hydroalkenylation of norbornene (bicyclo[2.2.1]hept-2-ene) can be performed in 93% e.e. using 1-methyl-2-(ethoxycarbonyl)ethenyl triflate 5 as alkenylation agent and Pd{(R)-binap}2 as chiral catalyst.
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