Journal of the American Chemical Society · 2012 · 42 citations · 35 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryCatalytic MechanismsHydrocarbon GenerationCarbon-hydrogen ActivationHydrogen Bonding In CatalysisHydrogen-bonding CatalysisHydrogenationHydrogenation ReactionsMolecular Hydrogenation ProcessesWater-mediated CatalysisWater-mediated Hydrogen Bonds
The catalytic carbon-carbon σ-bond activation and hydrogenation of [2.2]paracyclophane with water in a neutral reaction medium is demonstrated. The hydrogen from water is transferred to the hydrocarbon to furnish hydrogen enrichment in good yields.
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Cheves Walling · Accounts of Chemical Research · 1975 · 2.8K citations
Pharmacy, Chemistry, Toxicology +6
Activation of a carbon–carbon bond in solution by transition-metal insertion
Michael Gozin, Alexander Weisman, Yehoshua Ben‐David et al. · Nature · 1993 · 301 citations