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Conformational control in the 3,7-diazbicyclo[3.3.1]nonane system
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1985
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Conformational ControlEngineeringHeterocyclicNatural SciencesMolecular BiologyConformational StudyStructure ElucidationOrganic ChemistryComputational ChemistryMain Group ChemistryChemistryHeterocycle ChemistryPyramidal Bonding PatternsN AtomsBoat-chair Conformation
The twin-chair or boat-chair conformation of 3,7-diazabicyclo[3.3.1]nonaes can be selected by forming N,N′-derivatives in which the N atoms have planer or pyramidal bonding patterns, respectively, e.g. acyl substituents for the former and arylsulphonyl or alkyl for the latter.