Publication | Closed Access
Assembly of a Porous Three-Dimensional Coordination Polymer: Crystal Structure of {[La<sub>2</sub>(adipate)<sub>3</sub>(H<sub>2</sub>O)<sub>4</sub>]6H<sub>2</sub>O}<i><sub>n</sub></i>
181
Citations
33
References
1998
Year
Crystal StructureSupramolecular AssemblyEngineeringPorous PolymerChemistryWater MoleculesPolymersPolymer ChemistryMaterials ScienceInorganic ChemistryCovalent Bonded FrameworkOrganometallic PolymerCrystallographyHierarchical AssemblySelf-assemblyPolymer ScienceDehydration BehaviorCoordination PolymerInorganic PolymerPorous 3D
The structure and dehydration behavior of the porous 3D coordination polymer {[La2(adipate)3(H2O)4]6H2O}n are described. Each La3+ is coordinated by nine oxygen atoms belonging to five carboxylate ligands and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structure. Upon heating, this compound transforms reversibly into a nonporous lower hydrate.
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