Pd Nanoparticles Immobilized on Molecular Sieves by Ionic Liquids: Heterogeneous Catalysts for Solvent‐Free Hydrogenation

Jun Huang, Tao Jiang, Haixiang Gao, Buxing Han, Zhimin Liu, Weize Wu, Yanhong Chang, Guoying Zhao

Angewandte Chemie International Edition · 2004 · 234 citations · 36 references

Concepts

Abstract

A three-piece suite: The immobilization of a Pd-nanoparticle catalyst onto the surface of a molecular sieve by an ionic liquid (1,1,3,3-tetramethylguanidinium lactate) has been accomplished (see TEM image). The nanoparticle/ionic liquid/molecular sieve combination exhibits excellent synergistic effects that enhance the activity and durability of the catalyst for the hydrogenation of olefins.

References

36