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Chiral cyclohexanes from carbohydrates: successful carbocyclisation of a D-arabino-hex-5-enopyranoside derivative
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1984
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Enantioselective SynthesisEngineeringHeterocyclicBiochemistryGlycobiologyD-arabino ConfigurationOrganic ChemistryUseful Synthetic IntermediatesStereoselective SynthesisNatural Product SynthesisAsymmetric CatalysisChiral Substituted CyclohexanesBiomolecular EngineeringChiral Cyclohexanes
Carbocyclisation of a hex-5-enopyranoside of D-arabino configuration under modified Ferrier's conditions gave chiral substituted cyclohexanes, which are precursors of aminocyclitols and useful synthetic intermediates, in good yield and without side reactions.