Applied Physics Letters · 2012 · 64 citations · 33 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryEnergy MaterialsCathode MaterialsCell EncapsulationElectrochemical CellsElectrochemical Energy ConversionElectrode MaterialsElectrolytic CellsDelaminationElectrochemical StabilityElectrode Degradation MechanismsElectrode EncapsulationEncapsulationLight-emitting DevicesMaximum EfficacyPractical Stability
We present a functional and scalable encapsulation of light-emitting electrochemical cells (LECs), which results in a measured ambient operation of >400 h at a brightness of >300 cd/m2 with a maximum efficacy of 6 lm/W, and a linearly extrapolated ambient operation of ∼5600 h at >100 cd/m2. Our findings suggest that previous studies have underestimated the practical stability of appropriately encapsulated LECs. We also report that the dominant ambient degradation for non-encapsulated LECs is water-induced delamination of the cathode from the active layer, while encapsulated LECs in contrast are found to decay from spatial variations in the active layer composition.
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Polymer Light-Emitting Electrochemical Cells
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Natural Sciences, Materials Engineering, Materials Science +17
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