Michael additions of carbonucleophiles to butenone catalyzed by the non-hydride [Ru(O2CH)(CO)2(PPh3)]2 complex

Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Shinji Murai, Fumitoshi Kakiuchi, Shinya Sekine et al. · Nature · 1993 · 1.4K citations

Natural Sciences, Chemical Engineering, Chemistry +10

Elaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H Bond

Barry M. Trost, Katsuharu Imi, Ian W. Davies · Journal of the American Chemical Society · 1995 · 236 citations

Natural Sciences, Chemistry, Analytical Chemistry +7

Catalytic asymmetric synthesis with trans-chelating chiral diphosphine ligand TRAP: rhodium-catalyzed asymmetric Michael addition of .alpha.-cyano carboxylates

Masaya Sawamura, Hitoshi Hamashima, Yoshihiko Ito · Journal of the American Chemical Society · 1992 · 207 citations

Natural Sciences, Biochemistry, Chemistry +9

Synthesis of substituted furans by palladium-catalyzed cyclization of acetylenic ketones

Yukitoshi Fukuda, Hiroshi Shiragami, Kiitirô Utimoto et al. · The Journal of Organic Chemistry · 1991 · 199 citations

Natural Sciences, Chemistry, Biocatalysis +16

Ruthenium-catalyzed aldol and Michael reactions of nitriles. Carbon-carbon bond formation by .alpha.-C-H activation of nitriles.

Shun‐Ichi Murahashi, Takeshi Naota, Hiroshi Taki et al. · Journal of the American Chemical Society · 1995 · 187 citations

Natural Sciences, Chemistry, Catalysis +9