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Monochlorogallane: synthesis, properties, and structure of the dimer H<sub>2</sub>Ga(µ-Cl)<sub>2</sub>GaH<sub>2</sub>in the gas phase as determined by electron diffraction
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1988
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HalogenationInorganic ChemistryChemical EngineeringEngineeringAlkene MetathesisBiochemistryGas PhaseNatural SciencesElectron DiffractionDimer H2gaPredominant Vapour SpeciesMain Group ChemistryChemistryMolecular ChemistryChemical Properties
Monochlorogallane, synthesised by metathesis involving gallium(III) chloride and trimethylsilane, has been characterised by its spectroscopic and chemical properties; electron diffraction has established the structure of the dimer H2Ga(µ-Cl)2GaH2, the predominant vapour species at low pressure.