Chemistry - A European Journal · 2009 · 209 citations · 23 references
Natural SciencesChemistryMaterials ScienceComputational ChemistryOrganic ChemistryQuantum ChemistryChemical BondingCoordination ChemistryHeterocyclic ChemistryHeterocyclic CompoundsMolecular BondingMolecular Orbital TheoryC - H Bond FunctionalizationCarbene BondingCarbene Coordination ChemistryElectronic Structure Of Carbene ComplexesHeterocyclic MaterialsLewis Acid-base TheoryLewis Acidity
Diarsenic as a Lewis acid: An N-heterocyclic carbene stabilized diarsenic molecule [L:AsAs:L] (L:=:C{N(2,6-iPr2C6H3)CH}2) (see scheme) has been prepared by potassium/graphite reduction of [L:AsCl3]. The nature of the bonding in this molecule was probed by DFT computations.
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