Concepedia

The Role of AlF<sub>3</sub> Coatings in Improving Electrochemical Cycling of Li‐Enriched Nickel‐Manganese Oxide Electrodes for Li‐Ion Batteries

Yang‐Kook Sun, Min‐Joon Lee, Chong Seung Yoon, Jusef Hassoun, Khalil Amine, Bruno Scrosati

Advanced Materials · 2012 · 699 citations · 29 references

DOI

Concepts

Abstract

A Li[Li(0.19)Ni(0.16)Co(0.08)Mn(0.57)]O(2) cathode was coated with AlF(3) on the surface. The AlF(3)-coating enhanced the overall electrochemical characteristics of the electrode while overcoming the typical shortcomings of lithium-enriched cathodes. This improvement was attributed to the transformation of the initial electrode layer to a spinel phase, induced by the Li chemical leaching effect of the AlF(3) coating layer.

References

29

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries

Michael M. Thackeray, Sun-Ho Kang, Christopher S. Johnson et al. · Journal of Materials Chemistry · 2007 · 2K citations

, , +16

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni<sub>0.2</sub>Li<sub>0.2</sub>Mn<sub>0.6</sub>]O<sub>2</sub>

A. Robert Armstrong, Michael Holzapfel, Petr Novák et al. · Journal of the American Chemical Society · 2006 · 1.6K citations

, , +17

Understanding the Anomalous Capacity of Li/Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] Cells Using In Situ X-Ray Diffraction and Electrochemical Studies

Zhonghua Lu, J. R. Dahn · Journal of The Electrochemical Society · 2002 · 995 citations

, , +17

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries

Zhonghua Lu, Dean D. MacNeil, J. R. Dahn · Electrochemical and Solid-State Letters · 2001 · 933 citations

, , +17

The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes

Christopher S. Johnson, Ji‐Seon Kim, Chrissy Lefief et al. · Electrochemistry Communications · 2004 · 736 citations

, , +16