Concepedia

Novel Alkyne Carbene Tungsten Complexes

Rong‐Zhi Ku, Der‐Yi Chen, Gene‐Hsiang Lee, Shie‐Ming Peng, Shiuh‐Tzung Liu

Angewandte Chemie International Edition in English · 1997 · 36 citations · 18 references

DOI

Concepts

Abstract

Only alkyne and carbene ligands surround the tungsten atom in complexes 1 and 2. Complex 1, which has been characterized by X-ray crystallography, catalyzes the polymerization of diphenylacetylene (see below). L  PhC  CPh.

References

18

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Synthesis, Resolution, and Determination of Absolute Configuration of a Vaulted 2,2‘-Binaphthol and a Vaulted 3,3‘-Biphenanthrol (VAPOL)

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