Helvetica Chimica Acta · 1962 · 31 citations · 4 references
Protein ChemistryBioorganic ChemistryMe 2BiochemistryEngineeringNatural SciencesCme 2Organic ChemistryAbstract αChemistryChemical BiologyHalogenationEnzymatic ModificationChemical KineticsMolecular FragmentationBiomolecular Engineering
Abstract α,α‐Dimethyl γ‐dimethylaminoalkyl halides Me 2 NCH 2 CMe 2 X (X = Cl, Br, I) undergo fragmentation (43–47%) upon solvolysis in «80%» ethanol. The relative rates at 40° are 1, 38 and 113.
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