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The Core–Shell Approach to Formation of Ordered Nanoporous Materials
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2002
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Materials ScienceEngineeringNanoporous MaterialNanomaterialsNanotechnologySelf-assemblyPorous MembraneCore–shell ApproachPore SizeMicellePorous PolymerNmr TechniquesNanostructured PolymerNanostructure SynthesisChemistryWall Structure
Ordered nanoporous materials with uniform pore shape and wall structure have been prepared from selected diblock copolymers. Fine-tuning of the pore size and wall thickness is possible by controlling the micelle size (see Figure). The formation mechanism of these nanoporous structures is confirmed by both liquid- and solid-state 13C and 29Si NMR techniques.