C<sub>70</sub> Is More Stable than C<sub>60</sub>: Experimental Determination of the Heat of Formation of C<sub>70</sub>

Hans‐Dieter Beckhaus, Christoph Rüchardt, François Diederich, Carlo Thilgen, Hans‐Ulrich Ter Meer, Holger Mohn, Wolfgang H. Müller

Angewandte Chemie International Edition in English · 1994 · 102 citations · 18 references

Concepts

Abstract

C 70 , C 60 ,…, diamond, graphite. The accurate calorimetric determination of the standard heats of formation of highly pure C 60 and C 70 confirms the fundamental statements concerning the stability in the series of the allotropic forms of carbon predicted from calculations. MM3 force‐field calculations provide the best prediction of the experimental values.

References

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