Geophysical Research Letters · 1976 · 1.2K citations · 21 references
Natural SciencesEarth SciencesGeologyGeochemistryPetrologyPlanetary GeologyMantle GeochemistryMantle PetrologyPlutonic RocksGeochronology Of Crustal RocksGeologic ProcessesIsotopic EvolutionIsotopic Geochemistry Of The MantleMagma Source CharacterizationMantle Isotope GeochemistryMantle ReservoirsMantle Source Signatures
The decay of 147Sm to 143Nd enables 143Nd/144Nd to trace Sm/Nd fractionation over long geological times. The authors measured 143Nd/144Nd in terrestrial rocks of varying ages to characterize Nd isotopic evolution in crust and mantle. Mantle 143Nd/144Nd evolution shows Sm/Nd near chondritic values but with heterogeneity and distinct reservoirs, while crustal rocks have lower ratios, and oceanic tholeiites and alkali basalts originate from sources with 5–10 % higher Sm/Nd than chondrites, precluding derivation from long‑enriched light‑REE reservoirs.
The decay of 147 Sm to 143 Nd allows 143 Nd/ 144 Nd to be used to trace Sm/Nd fractionation in long time‐scale geologic processes. 143 Nd/ 144 Nd has been measured in terrestrial rock samples of different ages to establish the characteristics of Nd isotopic evolution in the crust and mantle. The evolution of 143 Nd/ 144 Nd in the mantle indicates Sm/Nd essentially equal to that of chondrites, and implies a chondritic REE distribution for the earth. Variations in 143 Nd/ 144 Nd do exist in the mantle, however, indicating Sm/Nd heterogeneity and the existence of distinct mantle reservoirs with characteristic 143 Nd/ 144 Nd. 143 Nd/ 144 Nd in average crustal rocks today is much lower than found in recent mantle samples and reflects their age and low Sm/Nd. Oceanic tholeiites and alkali basalt are derived from sources with Sm/Nd which has been 5‐10% greater than chondritic over the age of the earth. Alkali basalt can not be derived from mantle reservoirs which have been light REE‐enriched for long times.
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The Rare Earth Content and Origin of Alkali-Rich Basalts
Robert W. Kay, P. W. Gast · The Journal of Geology · 1973 · 417 citations
Meteoritic, solar and terrestrial rare-earth distributions
L. A. Haskin, Frederick A. Frey, Roman A. Schmitt et al. · Physics and Chemistry of the Earth · 1966 · 319 citations