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(N-Heterocyclic Carbene)PdCl<sub>2</sub>(TEA) Complexes: Studies on the Effect of the “Throw-Away” Ligand in Catalytic Activity
138
Citations
27
References
2011
Year
N-heterocyclic CarbeneInorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringNatural SciencesCoordination ComplexDiversity-oriented SynthesisOrganometallic CatalysisCatalysisCatalytic ActivityChemistryHeterocycle ChemistryMolecular ComplexInorganic SynthesisBuchwald–hartwig Reactions
The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki–Miyaura and Buchwald–Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented.
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