Synthesis, Characterization and Reactivity of<i>cis-cis-cis</i>[(C<sub>6</sub>H<sub>5</sub>)<sub>4</sub>Si<sub>4</sub>O<sub>4</sub>(OH)<sub>4</sub>] - Concepedia

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Synthesis, Characterization and Reactivity of<i>cis-cis-cis</i>[(C<sub>6</sub>H<sub>5</sub>)<sub>4</sub>Si<sub>4</sub>O<sub>4</sub>(OH)<sub>4</sub>]

75

Citations

27

References

1997

Year

Frank J. Feher, Joseph J. Schwab, Daravong Soulivong, Joseph W. Ziller

Main Group Chemistry

Materials ScienceInorganic ChemistryEngineeringHydrolytic CondensationAll-cis StructureChemistryInorganic MaterialCrystallographyInorganic SynthesisJ. F. BrownInorganic Compound

Abstract

The hydrolytic condensation of PhSiCl3 (H2 O/acetone, 0–5°C, 18 h) precipitates cis-cis-cis-[(C6 H5 )4 Si4 O4 (OH)4 ] (5a) as the sole crystalline product in approximately 40% yield. The all-cis structure, which was originally assigned by J. F. Brown

References

	Year	Citations

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