Light Harvesting as a Simple and Versatile Way to Enhance Brightness of Luminescent Sensors

TLDR

Indicator dye brightness in luminescent sensors can be amplified by adding brighter antenna dyes. The paper reviews how light harvesting can be applied to various reagent‑mediated optical sensing schemes. Antenna dye molecules absorb excitation light and transfer energy to indicator dyes, and the authors assessed this light‑harvesting strategy in ~250 nm thick sensor layers compared with conventional sensors. Light harvesting produces thin (<500 nm) sensor layers and nanometer‑sized particles with exceptionally high brightness compatible with powerful LEDs, and the approach was demonstrated for oxygen and ammonia sensors.

Abstract

The emissive output of indicator dyes in luminescent sensors can be amplified by the addition of antenna dyes with a higher brightness. The highly concentrated antenna dye molecules absorb the excitation light and transfer the energy to an indicator dye. This harvesting of light makes thin sensor layers (thickness <500 nm) and nanometer sized sensor particles with exceptionally high brightness and compatible with the most powerful LEDs available. The performance of sensor layers of ∼250 nm thickness employing light harvesting was investigated and compared with established sensors. The principle is demonstrated for oxygen and ammonia sensors. An overview of possible application of light harvesting to various reagent mediated optical sensing schemes is given.