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A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap
18
Citations
23
References
2013
Year
EngineeringNanostructured PolymerChemistryInorganic MaterialBand GapManganese-doped Polymeric FrameworkPolymersPolyoxotitanate NanoclustersPolymer ChemistryMaterials ScienceInorganic ChemistryDoped Polyoxotitanate NanoclustersManganese-doped Polyoxotitanate NanoclusterNarrow Band GapNanomaterialsPolymer ScienceCoordination PolymerInorganic PolymerFunctional MaterialsPolymer HybridOrganic-inorganic Hybrid Material
A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)3]4(OEt)12Br4}∞, has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.
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