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SYNTHESIS AND REACTION OF NEW TYPE I–N YLIDE, N-TOSYLIMINOIODINANE
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1975
Year
Diversity Oriented SynthesisEngineeringNatural SciencesImine CompoundsDiversity-oriented SynthesisOrganic ChemistryNitrene IntermediateChemistryNatural Product SynthesisNew Type I–nSynthetic ChemistryBiomolecular Engineering
Abstract (Diacetoxyiodo)arene reacts with p-toluenesulfonamide in the presence of base to give the new type I–N ylide, N-tosyliminoaryliodinane. In the decomposition of this ylide, the nitrene intermediate is proposed to be formed and react with nucleophiles to afford the imine compounds.