Concepedia

X-Ray Structural Characterization of a Monoorganotin Acid

J. W. A. M. JANSSEN, Jörg Magull, Herbert W. Roesky

Angewandte Chemie International Edition · 2002 · 72 citations · 22 references

DOI

Concepts

Abstract

An eighty-year-old question answered: The basic structural element of monoorganotin acids (see structure) is formed by cyclo-tristannoxanes in a chairlike conformation with ligands bonded to the Sn3O3 heterocycle in equatorial positions. The three axial hydroxy groups display a cis arrangement. Thus the fundamental structural element of this class of compounds is elucidated.

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