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The structural characterisation of Ph3PSe(Ph)I. The first charge transfer (CT) complex of a tertiary phosphine containing a pseudohalogen
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Citations
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References
1999
Year
Inorganic CompoundInorganic ChemistryTertiary PhosphineEngineeringCharge TransferBiochemistryNatural SciencesCoordination ComplexComplex Ph3pseMolecular BiologyOrganic ChemistryFirst Charge TransferMolecular ComplexChemistryCrystallographyInorganic SynthesisStructural BiologyStructural Characterisation
The reaction of 2 mol equivalents of triphenylphosphine with diphenyldiselenyldiiodine (Ph2Se2I2) produces the charge transfer (CT) complex Ph3PSe(Ph)I in quantitative yield; this compound represents the first report of a CT complex of a tertiary phosphine that contains a pseudohalogen.
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