Influence of silver nano‐additive amount on the supramolecular structure, porosity, and properties of polyacrylonitrile precursor fibers

Abstract

Abstract This work examines the influence of the amount of silver nanoparticles added to polyacrylonitrile spinning solutions on their rheological properties as well as the structure and properties of the fibers produced. The influence of the amount of silver nanoparticles on the supramolecular structure of nanocomposite polyacrylonitrile precursor fibers, their porosity, as well as thermal and tensile strength properties was determined. The distribution of the nano‐ additive in fiber cross‐sections and on the surface was estimated. It was found that the addition of silver nanoparticles to polyacrylonitrile precursor fibers in an amount of up to 1.5% does not cause a decrease in the susceptibility of the fiber matter to deformation at the drawing stage. The produced fibers were characterized by an increased total volume of pores of 0.35 cm 3 /g and tenacity of more than 34 cN/tex. Copyright © 2009 John Wiley & Sons, Ltd.