Asymmetric water-soluble diphosphines: synthesis and use in hydrogenation as their rhodium complexes of polyoxadiphosphines

Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine

Henri B. Kagan, Tuan-Phat Dang · Journal of the American Chemical Society · 1972 · 1K citations

Natural Sciences, Chemistry, Catalysis +7

Asymmetric hydrogenation. Rhodium chiral bisphosphine catalyst

B. D. Vineyard, William S. Knowles, M. J. Sabacky et al. · Journal of the American Chemical Society · 1977 · 827 citations

Natural Sciences, Chemistry, Catalysis +12

Catalysis by water-soluble phosphine complexes of transition metal ions in aqueous and two-phase media

Ferenc Joó, Zoltán Tóth · Journal of Molecular Catalysis · 1980 · 134 citations

Natural Sciences, Biochemistry, Chemistry +16

Synthesis of functional chelating diphosphines containing the bis[2-(diphenylphosphino)ethyl]amino moiety and the use of these materials in the preparation of water-soluble diphosphine complexes of transition metals

Ralph G. Nuzzo, Sharon L. Haynie, Michael E. Wilson et al. · The Journal of Organic Chemistry · 1981 · 110 citations

Natural Sciences, Chemistry, Medicinal Chemistry +12

Rhodium complexes of the water-soluble phosphine Ph2PCH2CH2NMe3+. Their complexes with hydride, olefin, and carbon monoxide ligands. Their use as olefin hydrogenation and hydroformylation catalysts in aqueous solution and in aqueous/organic solvent two-phase systems, and adsorbed on a cation-exchange resin

Richard T. Smith, R. Kurt Ungar, Laura J. Sanderson et al. · Organometallics · 1983 · 106 citations

Natural Sciences, Chemistry, Catalysis +11