Novel pyridinium salts as cationic thermal and photoinitiators and their photosensitization properties

Abstract

Abstract Novel pyridinium salts [ N ‐(α‐phenylbenzyl)‐, N ‐(1‐naphthylmethyl)‐, or N ‐cinnamyl p ‐ or o ‐cyanopyridinium hexafluoroantimonates] were synthesized by the reaction of p ‐ or o ‐cyanopyridine and the corresponding bromides followed by anion exchange with KSbF 6 . These pyridinium salts polymerized epoxy monomers at lower temperatures than previously reported for N ‐benzyl‐2‐cyanopyridinium hexafluoroantimonate. The o ‐substituted pyridinium salts showed higher activity than the p ‐substituted ones, and the crosslinked epoxy polymers cured with these initiators showed higher glass‐transition temperatures. These pyridinium salts photoinitiated radical polymerization as well as cationic polymerization. The photopolymerization was accelerated by the addition of aromatic ketones as photosensitizers. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1037–1046, 2002