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Experimental verification of the intermediacy and interconversion of ion–neutral complexes as radical cations dissociate
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1988
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Inorganic ChemistryChemical EngineeringChemical KineticsExperimental VerificationEngineeringIon ExchangeSimple AlcoholNatural SciencesRadical (Chemistry)Proton TransferRadical CationsIon–neutral ComplexesMolecular ComplexChemistryInterfacial ChemistrySpecific Hydrogen ExchangeIon StructureIon Process
Specific hydrogen exchange provides experimental verification of the intermediacy of ion–neutral complexes in the reactions of simple alcohol and ether radical cations; interconversion of ion–neutral pairs can occur when loss of alkyl radicals and loss of alkane molecules have similar energy requirements.