Publication | Closed Access
[{Fe(CO)<sub>3</sub>}<sub>4</sub>{SnI}<sub>6</sub>I<sub>4</sub>]<sup>2−</sup>: The First Bimetallic Adamantane‐Like Cluster
17
Citations
27
References
2012
Year
Materials ScienceInorganic ChemistryMagnetic PropertiesBond-length ConsiderationsEngineeringCluster ScienceCondensed Matter PhysicsCluster ChemistryMain Group ChemistryDft CalculationsChemistryIonic-liquid-based SynthesisInorganic MaterialInorganic SynthesisInorganic Compound
Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations.
| Year | Citations | |
|---|---|---|
Page 1
Page 1