Concepedia

INDIUM-MEDIATED BARBIER REACTIONS OF AZIDES: A FACILE SYNTHESIS OF<i>N</i>-ALLYLAMINE DERIVATIVES

J. S. Yadav, Ch. Madhuri, B. V. Subba Reddy, G. Sudhakar Reddy, Gowravaram Sabitha

Synthetic Communications · 2002 · 22 citations · 18 references

DOI

Concepts

Abstract

ABSTRACT N-Allylic amines are conveniently prepared in high yields by the reaction of azides with allylindium reagents in the presence of sodium iodide in DMF at ambient temperature.

References

18

Organic syntheses using indium-mediated and catalyzed reactions in aqueous media

Chao‐Jun Li, Tak Hang Chan · Tetrahedron · 1999 · 519 citations

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Aqueous Barbier-Grignard type reaction: Scope, mechanism, and synthetic applications

Chao‐Jun Li · Tetrahedron · 1996 · 490 citations

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Synthetic Organoindium Chemistry: What Makes Indium so Appealing?

Pedro Cintas · Synlett · 1995 · 291 citations

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Organometallic reactions in aqueous media with indium

Chao‐Jun Li, Tak Hang Chan · Tetrahedron Letters · 1991 · 264 citations

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Addition of Allylindium Reagents to Aldehydes Substituted at C<sub>α</sub> or C<sub>β</sub> with Heteroatomic Functional Groups. Analysis of the Modulation in Diastereoselectivity Attainable in Aqueous, Organic, and Mixed Solvent Systems

Leo A. Paquette, Thomas M. Mitzel · Journal of the American Chemical Society · 1996 · 165 citations

, , +7