Concepedia

Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(ii) complex

Jeremy M. Smith, R.J. Lachicotte, Patrick L. Holland

Chemical Communications · 2001 · 116 citations · 19 references

DOI

Concepts

Abstract

The coordination number of the metal in iron(II) beta-diketiminate complexes can be tuned through the size of the alkyl substituents on the ligand backbone.

References

19

Crystallographic structure and functional implications of the nitrogenase molybdenum–iron protein from Azotobacter vinelandii

Jongsun Kirn, Douglas C. Rees · Nature · 1992 · 611 citations

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Single-Site Catalysts for Ring-Opening Polymerization:  Synthesis of Heterotactic Poly(lactic acid) from <i>rac</i>-Lactide

Ming Cheng, Athula B. Attygalle, Emil B. Lobkovsky et al. · Journal of the American Chemical Society · 1999 · 590 citations

, , +16

Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene

Chunming Cui, Herbert W. Roesky, Hans‐Georg Schmidt et al. · Angewandte Chemie International Edition · 2000 · 499 citations

, , +9

Catalytic Reactions Involving C<sub>1</sub> Feedstocks:  New High-Activity Zn(II)-Based Catalysts for the Alternating Copolymerization of Carbon Dioxide and Epoxides

Ming Cheng, Emil B. Lobkovsky, Geoffrey W. Coates · Journal of the American Chemical Society · 1998 · 477 citations

, , +13

Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization

Jerald Feldman, Stephan J. McLain, Anju Parthasarathy et al. · Organometallics · 1997 · 345 citations

, , +12