Publication | Open Access
Cobalt-Catalyzed Synthesis of Tertiary Azides from α,α-Disubstituted Olefins under Mild Conditions Using Commercially Available Reagents
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2007
Year
Chemical EngineeringEngineeringTertiary AzidesNatural SciencesCobalt-catalyzed SynthesisDiversity-oriented SynthesisOrganic ChemistryAvailable Azide SourcesOrganometallic CatalysisCatalysisChemistryα-Disubstituted OlefinsCobalt-catalyzed Hydroazidation ReactionSynthetic Chemistry
The use of commercially available azide sources is presented for the cobalt-catalyzed hydroazidation reaction. α,α-Disubstituted olefins with a variety of functional groups were employed as substrates, providing tertiary azides in useful yields.