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Preparation and Characterization of Ni/Al‐Layered Double Hydroxide
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1999
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Aluminium NitrideEngineeringElectrode-electrolyte InterfaceChemistryChemical EngineeringElectrochemical SocietyElectrochemical BehaviorMaterials ScienceInorganic ChemistryNi/al‐layered Double HydroxideSolid-state IonicBattery Electrode MaterialsSurface ElectrochemistryEnergy StorageCrystallinity DependenceElectrochemical ProcessElectrochemistrySurface ScienceBatteries
The electrochemical behavior of chemically prepared α‐phase Al‐substituted was investigated in relation to its crystallinity. α‐Phase samples with 5–20% Al were prepared by precipitation, and the crystallinity was tailored by changing the metal/alkali ratio or the aging temperature. A highly crystallized sample was obtained without controlling the reaction pH. Both the utilization and half‐discharge potential increased as the sample crystallinity improved. A maximum capacity of 381 mAh/g and utilization of 190% were obtained. The crystallinity dependence of the cell performance was explained by the reduction of polarization because of a more ordered structure which led to a faster solid‐state reaction. © 1999 The Electrochemical Society. All rights reserved.